waecE-LEARNING
Chemistry Paper 2 (Essay) ,May/June 2014  
Questions:   1 2 3 4 5  Main
General Comments
Weakness/Remedies
Strength













































































Question 5

 (a)       (i)         Define the term functional group.

                        (ii)        Name the functional groups present in the following compound:


                        (i)         Name compound Q

                        (ii)        Write the balanced equation for the complete combustion of                                                            compound Q

                        (iii)       What type of reaction will compound Q undergo with chlorine?

                        (vi)       Draw the structure of the alkene that is an isomer of
                                    compound Q.                                                                               [5 marks]

                        (c)        A chemistry student was provided with four samples of organic                                                      compounds, A, B, C and D.

            Samples A and B each decolourized bromine in tetrachloromethane but only sample B      reacted with a solution of ammoniacal silver trioxonitrate (V) to give a white precipitate.
            Sample D reacted with sodium trioxocarbonate (IV) to liberate carbon (IV) oxide.  
            When heat was applied to the mixture of samples C and D in a test tube and drops
            of concentrated tetraoxosulphate (VI) acid added, a product with a fruity odour
            was formed.

            (i)         Name the family of organic compounds to which samples A, B, C and
                        D belong.

            (ii)        State why samples A and B reacted with bromine in tetrachloromethane.

            (iii)       State the reason why sample B gave a white precipitate with the solution
                        of ammoniacal silver traioxonitrate (V).

            (iv)       Give the name of the reactions between samples C and D.

            (v)        State the two roles of the concentrated tetraoxosulphate (VI) acid in the
                        reaction in 5(a)(iv)                                                                                     [10 marks]

            (d)       (i)         Describe briefly the production of biogas using a biogas
                                    generator.

                        (ii)        State two uses of biogas                                                                 [5 marks]
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OBSERVATION
 

A good number of candidates attempted this question and the performance was fair.

            In part (a), majority of the candidates were able to give the definition of functional
            group correctly.  However, some candidates could not identify the functional group
            in the structure.

            In part (b), majority of the candidates could not state the type of reaction that Q
            would undergo with Cl2.   Also, most of the candidates could not draw the structure or
            the alkene that is an isomer of compound Q.

            In part (c), majority of the candidates that attempted this part could not state the reason
            why B gave white precipitate with ammoniacal AgNO3 solution.  Only a few
            candidates gave the name of the reaction between C and D as esterification.

            In part (d), majority of the candidates could not describe the production of biogas using
            a biogas generator.  However, some were able to give uses of biogas.

            The expected answers include:

            (a)        (i)         Functional group is a bond, an atom or group of atoms which
            give an organic compound its characteristic chemical properties                                                      
            (ii)        alkanol                            
                        alkanoate                                                                                  
         

        (b)            (i)         Cyclopropane     
                        (ii)        2C3H6 + 9O2 → 6CO2 + 6H2O            
                                   
                        (iii)       Substitution reaction     
   
                                                                                                                                     
            (c)        (i)         Sample A  =  alkene      
                                    Sample B  =  alkyne      
                                    Sample C  =  alkanol      
                                    Sample D =   alkanoic acid      

                        (ii)        Both samples A and B are unsaturated compounds                
                                   

                        (iii)       Sample B is a terminal alkyne            

                        (iv)       Esterification              
                        (v)        -           as a catalyst    
                                    -           to remove water  
                                                Accept dehydration                                                                          

            (d)       (i)         The organic waste  is fed into a biodigester where
            different kinds of bacteria convert the decaying
            matter into biogas CH4 / CO2 / H2 / CO through
            the process of anaerobic decomposition.  

                        (ii)        -           for cooking/fuel
                                    -           for heating/fuel
                                    -           for lighting/fuel
                                    -           as residue for fertilizer

                                    -           generating electricity
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