Question 2
    
(a)        How many atoms are there in 10.0 g of CaCO3?
      [C = 12.0; O =  16.0; Ca = 40.0; Avogadro’s constant = 6.02 x 1023]
      [5  marks]
(b)
(i)         Write a balanced chemical equation to  show the acidic nature of each of  the 
      following  compounds when reacted with sodium:
      (I)        C2H2;
      (II)       C2H5OH.
            (ii)        name the major  product in each of the reactions in 2(b)(i).
      [6  marks]
      (c)        Consider the following  reaction scheme:
         
(i)         Draw the structures of compounds X and Y.
      (ii)        What happens when bromine water is added  to compound X and Y respectively.
      (iii)       Explain the answer given in 2(c)(ii).
(d)        Magnesium reacts  with aqueous solution of an acid to liberate hydrogen gas.
            Write  the:
            (i)         half-reaction equations;
      (ii)        overall reaction equation.
      [3  marks]
      (e)        (i)         State two differences between a  mixture and a compound.
      (ii)        Classify each of the following substances as an element, a mixture or a  compound: quicklime; gold; soil.
      An element:
      A mixture:
      A Compound:
    
Observation
Majority of the candidates responded to the question and their performance was average.
In part (a), few candidates calculated the number of atoms that are in 10.0 g of CaCO3.
In part (b), majority of the candidates could not write a balanced equation to show the acidic nature of C2H2 when reacted with sodium.
In part (c), majority of the candidates could not draw the structures of the compounds X and Y respectively.
In part (d), majority of the candidates could not write the half-reaction equation when magnesium reacts with aqueous solution of an acid to liberate hydrogen gas.
In part (e),  majority of the candidates stated the differences between a mixture and a  compound.
The expected  answers include:
  (a)      Molar  Mass of CaCO3 = 40 + 12 + 3 (16)      
    = 100 g mol-1
:. 10.0 g CaCO3 = 10/100
= 0.1 mol
            no. of atoms per molecule = 5 
           ⇒  no of atoms in 10.0g CaCO3 = 5 x 0.1 x 6.02 x 1023  
    = 3.01 x 1023 atoms
                                                                                                                                      
(b)(i)           I.          C2H2 + 2Na → Na2C2(s)  + H2(g) (2)
    Or  2C2H2  + 2Na → 2C2HNa + H2
                       II.        2C2H5OH + 2Na → 2C2H5ONa(s)  + H2(g)
    
    (ii)      
I.          Sodium Carbide / Sodium ethynide    
    II.        Sodium ethoxide

(ii) Compound X decolourises bromine water but compound Y does not decolourise bromine water.
(iii) Because compound X is an unsaturated compound and compound Y is a saturated compound
(d)(i) Mg(s) → Mg2+(aq)+ 2e- (1)
2H+(aq) + 2e- → H2(g) (1)
      (ii)  Mg(s)  +  2H+(aq) →  Mg2+(aq) +  H2(g)(1)
                                                                            
    (e)(i)
Mixture  | 
      Compound  | 
    
-     Homogeneous or heterogeneous  | 
      -     Only homogeneous  | 
    
                                                                                                            
    (ii)  quick lime – compound
    Gold  – element  
    Soil  – mixture